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Gift Wrapping Five Oranges Has Outwitted the Best Minds in Mathematics for Generations
(www.scientificamerican.com)
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Yeah, arbitrary sphere packing problems turn out to be quite tricky. Thankfully there are some nice simple cases that actually have physical relevance, like 3D packing of infinite regular spheres (FCC/HCP packings win). Edit: actually proving that isn't exactly easy, but the fact that that's the densest packing of atoms we observe in nature was a good hint!
But when you try to generalize things in some way... Well, the article does a pretty good job explaining why it gets hard!