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Fully Charged in Just 6 Minutes – Groundbreaking Technique Could Revolutionize EV Charging
(scitechdaily.com)
This is a most excellent place for technology news and articles.
The power lines in the cable are disconnected inside the charger by a contactor until communication with the car is confirmed established with a handshake, and then it connects power to the cable. If the communication with the car drops at any point, the contactor disconnects the power to the cable. It requires both effort and knowledge to bypass this design, it basically can't happen accidentally.
Also, the cables you mention are that large, because they're passively cooled, DC car chargers have watercooled cables so they can be much thinner without overheating. And at 4kV you're looking at significantly different insulation thickness as well, compared to the 400-800V that electric cars use.