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Cars have micro channel evap coils, central does as well. Not sure about ductless however, probably not unless it's outdoor
Reversing valve is typically in heat pump applications, allows the refrigerant to flow in reverse effectively supplying heat to the space instead of extracting it.
I'm used to central AC mostly, but I have worked with and used ductless, I'm not overly a fan myself. Controls are too much. I like simple relays and switches, less logic on the board. I want to be able to repair failures easily should they arise.