Cast Iron

Strictly speaking it's still porous at the microscopic level

Same as it does on a rough surface.

You get the oils polymerizing, which is going to stick to pretty much anything, no matter how smooth it looks. The surface isn't microscopically smooth, there's still roughness.

However, it wouldn't matter if it was perfectly smooth. The bonding between the iron and the oils isn't purely mechanical. It bonds on a molecular level, meaning that the little bits on the atoms of the polymerized oil make sweet, slippery love to the little bits on the atoms of the pan.

A smoother surface is actually better. You don't have as irregular a surface on the polymer, and there's less gaps where they contact the metal. Which, ideally, you'll be applying very thin coats and prevent gaps, but it's never a perfect process.

Sanding down a pan before seasoning improves the bond, improves the cooking surface, and makes it easier to season.

You ever use a stainless steel pan of some kind and have oil get solid-ish on it? It leaves that layer of brownish, maybe amber stuff that's slick and hard to scrape off. It's the same thing. You can polish stainless still to a mirror finish and that will still happen, and it'll still be difficult to remove.

When it comes to that, a rough surface is more likely to chip, flake, or otherwise fail.

Your best seasoned pan is going to be sanded smooth, then seasoned with food grade flax oil (though it is by no means the only option, it's the best drying oil that's food grade). You'll cycle it three to five times, depending on your freedom to do so. Then you'll have very low stick, heat resistant surface.

Now, nothing is perfect. If you can't get flaxseed, stuff like canola that's semi hardening will work almost as well (most of the time, you can't tell the difference until or unless you abuse the hell out of the pan). If you can't get that, any oil that's safe to eat will get the job done to some degree, so long as it's heat reactive at oven temps. Which, if you can't get flaxseed, the chances of being able to source anything that unusual isn't likely to begin with.

Same way it sticks on every carbon steel pan which are all smooth.