this post was submitted on 05 Jul 2023
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When I was cleaning a heatsink from an older laptop, the aluminum, and I think also a bit of copper, started to disintegrate very quickly and sometimes violently. I used a cleaning solution that was made for removing thermal paste and cleaning CPUs and PCBs. After some time, the only thing left of the heatsink was some grey powder or ash. I have cleaned many heatsinks and CPUs with it before, and this never happened, and I can't reproduce it.

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[–] Sharpiemarker@feddit.de 4 points 1 year ago

Copper metal "dissolves" in nitric acid (HNO3). Actually, the nitrate ion oxidizes the copper metal to copper (II) ion while itself being transformed to NO2 gas in the process; the copper (II) ion then binds to six water molecules.

Source

[–] BlueBlueSky@discuss.tchncs.de 3 points 1 year ago* (last edited 1 year ago) (3 children)

It looks like you are using this one: ArctiClean 1

Which seems to be specifically made for this application and supposedly consists of “citrus and soy based solvents”. Aluminium is solved by highly acidic (like sulphuric acid) and highly basic (like sodium hydroxide) solutions. Which it really doesn’t sound like until it somehow broke down in a way it got more potent.

Was it maybe a specific thermal paste with a metal like mercury or gallium inside? Supposedly they can quickly dissolve aluminium. Of course, I don’t know what happened but maybe it was dissolved by the cleaning solution and then rapidly reacted with the Aluminium of the heat sink. If so, that would still make me wonder about the bubbling and foaming when the cleaning solution comes in contact with the left overs.

[–] MightBeAlpharius@lemmy.world 4 points 1 year ago (1 children)

I would assume that nobody makes thermal paste out of anything terribly reactive, but... That .gif looks like something out of a NileRed video.

IIRC, gallium makes aluminum get super brittle, which might cause it to crumble like that; but the foaming makes me think that the heat sink might have managed to oxidize all the way through, and it's aluminum oxide reacting with the cleaner.

[–] kaupas24@kbin.social 2 points 1 year ago

Ye this looks like aluminium that's reacted to gallium